高分子化学原理

内容简介

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It was the author’s privilege to hold the George Fisher Baker Nonresident Lectureship in Chemistry at Cornell University during the spring of 1948.This book had its inception at that time.The uncompleted manuscript was laid aside shortly thereafter, and the work was not resumed until 1951.During the intervening years much new material became available from the ever-increasing literature, and major revision of manuscript and outlines consequently was necessary.The momentum of extensive investigations on the kinetics of addition polymerization, undertaken in various laboratories at the close of the war, carried this phase of the subject to an advanced stage of development. The material on dilute polymer solutions, appearing in the later chapters, had to be completely recast and expanded in the face of recent theories and experiments.The book consequently goes considerably beyond the Baker lectures both in scope and in the inclusion of new developments. …

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目录

PrefaceCHAPTER Ⅰ HISTORICAL INTRODUCTl0N　1.Early Investigations on NaturaUy Occurring Polymers　2.Early Encounters with Condensation Polymers　3.Vinyl Polymers　4.Rise of the Macromoleoular HypothesisReferences.CHAPTER Ⅱ TYPES 0F POLYMERIC SUBSTANCES:DEFINITIONS AND CLASSIFICATIONS　1.Primary Definitions　2.Classification of Polymers　3.Condensation Polymers and Condensation Polymerization　4.Addition Pobrmers from Unsaturated Monomers　5.Polymerization of Cyclic Compounds　6.Anomalous Conden8ation Polymerizations　7.Inorganic Polymers　8.Concluding Remarks on the Structure and Properties of High PolymersReferences.CHAPTER Ⅲ MOLECULAR SIZE AND CHEMICAL REACTIVITY;PRINCIPLES OF CONDENSATION POLYMERIZATION　1.Chemical Reactivity in Homologous Series of Monomeric Com—pouuds2.Theory of the Reactivity of Large Molecules3.Kinetics of Condensation Polymerization4.Kinetics of Degradation of Condensation Polymers　　4a.Hydrolysis of Cellulose and Cellulose Derivatives4b.Hydrolysis of Polyamides　 4c.Alcoholysis of Polyesters4d.Interchange Reactions in Condensation Polymers5.Molecular Weights of Linear Condensation Polymers6.Ring Formation vs.Chain Polymerization7.Summary and Conclusions: The Principle of Equal Reactivity of All Functional GroupsReferences.CHAPTER Ⅳ POLYMERIZATION OF UNSATURATED MONOMERS BY FREE RADICAL MECHANISMS　1.The Conversion of Monomer to Polymer　　1a.Kinetic Scheme for Polymerization in the Presence of an Initiator1b.Dependence of Initial Rates on the Concentrations of Initi-ator and Monomer1c.Initiator Efficiencies1d.Evaluation of Parameters1e.The Course of the Conversion of Monomer to Polymer;Autoacceleration1f.Kinetics of Thermal Polymerization　2.Chain Lengths2a.Kinetic Chain Length and Degree of Polymerization2b.Kinetics of Chain Transfer.2c.Chain Transfer in Undiluted Monomer; Evaluation of Parameters2d.Chain Transfer with Solvents2e.Dependence of the Degree of Polymerization on Tempera-ture2f.Regulators　3.Absolute Values of the Rate Constants for Individual Steps3a.Methods for Determining the Mean Lifetime of an Active Center.3b.Experimental Results　4.Inhibition and Retardation of Polymerization4a.Reaction Mechanisms4b.Kinetics of Inhibition and Retardation4c.Allylic Polymerization; AutoinhibitionReferences.CHAPTER Ⅴ COPOLYMERIZATION,EMULSION POLYMERIZATION AND IONIC POLYMERIZATIONCHAPTER Ⅵ THE STRUCTURE OF VINYL POLYMERSCHAPTER Ⅶ DETERMINATION OF MOLECULAR WEIGHTSCHAPTER Ⅷ MOLECULAR WEIGHT DISTRIBUTIONS IN LINEAR POLYMERSCHAPTER Ⅸ MOLECULAR WEIGHT DISTRIBUTIONS IN NONLINEARCHAPTER Ⅹ CONFIGTURATION OF POLYMER CHAINSCHAPTER Ⅺ RUBBER ELASTICITYCHAPTER Ⅻ STATISTICAL THERMODYNAMICS OF POLYMER SOLUTIONSCHAPTER XIII PHASE EQUILIBRIA IN POLYMER SYSTEMSCHAPTER XIV CONFIGURATIONAL AND FRICTIONAL PROPERTIES OF THE POLYMER MOLECULE IN DILUTE SOLUTIONGLOSSARY OF PRINCIPAL SYMBOLSAUTHOR INDEXSUBJECT INDEX

封面

书名:高分子化学原理

作者:Paul J. Flory[同作者作品]

页数:672

定价:¥68.0

出版社:世界图书出版公司

出版日期:2003-06-01

ISBN:9787506260169

PDF电子书大小:148MB 高清扫描完整版